Baldissera MD, Souza CF, De Matos AFIM, Baldisserotto B, Stefani LM, da Silva AS. • Diterpenes: 4 isoprene units, 20 carbon atoms. In: Cane DE (ed) Comprehensive natural products chemistry:isoprenoids including carotenoids and steroids. Academic Press, New York, p 383, West CA (1981) Biosynthesis of diterpenes. Elsevier Science, Oxford, Vol 2, p 267, Yamaguchi S, Saito T, Abe H, Yamane H, Murofushi N, Kamiya Y (1996) Plant J 10:203, Yamaguchi S, Sun T-P, Kawaide H, Kamiya Y (1998) Plant Physiol 116:1271, Kawaide H, Imai R, Sassa T, Kamiya Y (1997) J Biol Chem 272:21706, Funk C, Croteau R (1994) Arch Biochem Biophys 308:258, LeFever RE, Stofer Vogel B, Croteau R (1994) Arch Biochem Biophys 313:139, Ravn MM, Coates RM, Jetter R, Croteau R (1998) Chem Commun 21, Stofer Vogel B, Wildung M, Vogel G, Croteau R (1996) J Biol Chem 271:23262, Wendt KU, Schulz GE (1998) Structure 6:127. | Epub 2013 Apr 28. In: Porter JW, Spurgeon SL (eds) Biosynthesis of isoprenoid compounds. , "Sesquiterpene Lactones and their toxicity to livestock", "Biosynthesis of polyketide-terpenoid (meroterpenoid) metabolites andibenin B and andilesin A in Aspergillus variecolor", https://en.wikipedia.org/w/index.php?title=Sesquiterpene&oldid=984416607, Creative Commons Attribution-ShareAlike License, Iridoid glycosides (iridoids bound to a sugar), Terpene synthase enzymes (many), having in common a, This page was last edited on 20 October 2020, at 00:29.
Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. Epub 2017 Sep 19. Examples include longifolene, copaene and the alcohol patchoulol. | Wiley, New York, Vol 1, p 375, Wise ML, Croteau R (1999) Monoterpene biosynthesis. Terpenes are secreted by many plants and animals in order to … Detailed structural and functional evaluation of four representative monoterpene, sesquiterpene, and diterpene synthases is also presented. 2017 Nov;24(31):24708-24713. doi: 10.1007/s11356-017-0219-4. Part of Springer Nature. VCH, Weinheim Germany, p 263, Croteau R (1992) Monoterpene biosynthesis:cyclization of geranyl pyrophosphate to (+)-sabinene. 2013 Jul;96(7):4235-41. doi: 10.3168/jds.2012-6502. Elsevier Science, Oxford, Vol 2, p 97, Cane DE (1999) Sesquiterpene biosynthesis:cyclization mechanisms. NLM Most callus and suspension cultures derived from explants of herbaceous plants and trees that produce mono and sesquiterpenes do not accumulate products under conventional conditions. Lin SR, Chang CH, Hsu CF, Tsai MJ, Cheng H, Leong MK, Sung PJ, Chen JC, Weng CF. Purinergic system as a potential target for inflammation and toxicity induced by thymol in immune cells and tissues. Epub 2019 Jul 15. | In: Cane DE (ed) Comprehensive natural products chemistry:isoprenoids including carotenoids and steroids. He S, Zhang C, Zhou P, Zhang X, Ye T, Wang R, Sun G, Sun X. Int J Mol Sci. Essential oil; Herb-induced liver injury; Oxidative stress; Reactive metabolites; Terpenes. Most of these terpenes easily enter the human body by oral absorption, penetration through the skin, or inhalation leading to measurable blood concentrations. This is a preview of subscription content, Buckingham J (ed) (1998) Dictionary of natural products on CD-ROM, vol 6.1. Elsevier Science, Oxford, Vol 2, p 155, MacMillan J, Beale MH (1999) Diterpene biosynthesis. Epub 2018 Jul 31. • Triterpenes: 6 isoprene units, 30 carbon atoms. Especially terpenes, that are important components of essential oils with proved hepatotoxicity, should deserve more attention. In: Law JH, Rilling HC (eds) Methods in enzymology — steroids and isoprenoids. Sesquiterpenes are found naturally in plants and insects, as semiochemicals, e.g. Intensive research in terpenes metabolism and toxicity represent the only way to reduce the risk of liver injury induced by essential oils and other terpenes-containing products. J Environ Sci Health C Environ Carcinog Ecotoxicol Rev. With the addition of a third ring, the possible structures become increasingly varied. In general, sesquiterpenes are colorless, are insoluble in water and are more aromatic, less volatile and have higher boiling points than monoterpenes.
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